The metallacyclopentane–olefin interchange reaction
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چکیده
منابع مشابه
A Demonstration of the Reactivity-Selectivity Principle for the Thiol--Disulfide Interchange Reaction
Equilibrium constants for the reaction of aryl thiol anions with hydroxyethyl disulfide have been measured which, along with literature data, demonstrate a slope of 1.21 for a plot of log KS(R'S+ RSSR ¢ R'SSR + -SR) vs pKa. Rate constants were measured also for these endothermic reactions of aryl thiol anions with hydroxyethyl disulfide and also for the exothermic reactions of alkyl thiol anion...
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ژورنال
عنوان ژورنال: J. Chem. Soc., Chem. Commun.
سال: 1977
ISSN: 0022-4936
DOI: 10.1039/c39770000864